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Safety Data Sheets (SDS) Explained -

Prepare a risk assessment report for Streakers Hair and Beauty Salon, focusing on identifying hazards, assessing risks, and recommending controls to ensure a safe working environment.

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Added on  2022-08-21

Safety Data Sheets (SDS) Explained -

Prepare a risk assessment report for Streakers Hair and Beauty Salon, focusing on identifying hazards, assessing risks, and recommending controls to ensure a safe working environment.

   Added on 2022-08-21

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Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1

03/05/2014 EN (English) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form
: Substance
Substance name
: Formaldehyde, 37% w/w
CAS No
: 50-00-0
Product code
: VT310
Formula
: CH2O
Synonyms
: formic aldehyde, 37% / formol, 37% / methanal, 37% / methyl aldehyde, 37% / methylene glycol,
37% / methylene oxide, 37% / oxomethane, 37% / oxomethylene, 37% / paraform, 37% /
tetraoxymethylene, 37%

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
: Chemical intermediate
Disinfectant
Laboratory chemical

1.3. Details of the supplier of the safety data sheet

Val Tech Diagnostics, A Division of LabChem Inc
Jackson's Pointe Commerce Park Building 1000
1010 Jackson's Pointe Court
Zelienople, PA 16063
T 412-826-5230
F 724-473-0647

1.4. Emergency telephone number

Emergency number
: CHEMTREC: 1-800-424-9300 or 011-703-527-3887
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

GHS-US classification

Flam. Liq. 3
H226
Acute Tox. 4 (Oral)
H302
Acute Tox. 3 (Inhalation)
H331
Skin Corr. 1B
H314
Eye Dam. 1
H318
Skin Sens. 1A
H317
Carc. 1B
H350
Aquatic Acute 2
H401
2.2. Label elements

GHS-US labelling

Hazard pictograms (GHS-US)
:
GHS02
GHS05 GHS06 GHS08
Signal word (GHS-US)
: Danger
Hazard statements (GHS-US)
: H226 - Flammable liquid and vapour
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H331 - Toxic if inhaled
H350 - May cause cancer (Inhalation)
H401 - Toxic to aquatic life

Precautionary statements (GHS-US)
: P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking
Safety Data Sheets (SDS) Explained -_1
Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

03/05/2014 EN (English) 2/12

P233 - Keep container tightly closed
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical, ventilating, lighting equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P260 - Do not breathe mist, vapours, spray
P264 - Wash exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear protective clothing, protective gloves, eye protection, face protection
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 - IF exposed or concerned: Get medical advice/attention
P310 - Immediately call a POISON CENTER or doctor/physician
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention
P363 - Wash contaminated clothing before reuse
P370+P378 - In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for
extinction
P403+P233 - Store in a well-ventilated place. Keep container tightly closed
P235 - Keep cool
P405 - Store locked up
P501 - Dispose of contents/container to comply with local, state and federal regulations

2.3. Other hazards

Other hazards not contributing to the
classification

:
None under normal conditions.
2.4. Unknown acute toxicity (GHS-US)

No data available

SECTION 3: Composition/information on ingredients

3.1. Substance

Substance type
: Multi-constituent
Name
: Formaldehyde, 37% w/w
CAS No
: 50-00-0
EC no
: 200-001-8
EC index no
: 605-001-00-5
Name
Product identifier % GHS-US classification
Water
(CAS No) 7732-18-5 48 - 53 Not classified
Formaldehyde
(CAS No) 50-00-0 37 Acute Tox. 1 (Inhalation:gas),
H330

Carc. 1A, H350

Methanol
(CAS No) 67-56-1 10 - 15 Flam. Liq. 2, H225
Acute Tox. 3 (Oral), H301

Acute Tox. 3 (Dermal), H311

Acute Tox. 3 (Inhalation), H331

STOT SE 1, H370

Full text of H-phrases: see section 16

3.2. Mixture

Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general
: Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with
laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting:
prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up).
Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain.
Depending on the victim's condition: doctor/hospital.
Safety Data Sheets (SDS) Explained -_2
Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

03/05/2014 EN (English) 3/12

First-aid measures after inhalation
: Remove the victim into fresh air. Immediately consult a doctor/medical service.
First-aid measures after skin contact
: Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take
victim to hospital.

First-aid measures after eye contact
: Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take
victim to an ophthalmologist.

First-aid measures after ingestion
: Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre
(www.big.be/antigif.htm). Ingestion of large quantities: immediately to hospital. Take the
container/vomit to the doctor/hospital. Do not give chemical antidote. Doctor: gastric lavage.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation
: Runny nose. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. EXPOSURE TO HIGH CONCENTRATIONS: Possible oedema of the upper
respiratory tract. Possible laryngeal spasm/oedema. Respiratory difficulties. Risk of lung
oedema.

Symptoms/injuries after skin contact
: Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact
: Corrosion of the eye tissue.
Symptoms/injuries after ingestion
: Nausea. Vomiting. Diarrhoea. AFTER ABSORPTION OF HIGH QUANTITIES: Central nervous
system depression. Dizziness. Blood in vomit. Blood in stool. Shock. Disturbances of
consciousness. Change in the haemogramme/blood composition. Change in urine composition.
Urine discolouration.

Chronic symptoms
: ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Skin
rash/inflammation. Coughing. Possible inflammation of the respiratory tract. Respiratory
difficulties.

4.3. Indication of any immediate medical attention and special treatment needed

Obtain medical assistance.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
: Preferably: water spray. Alcohol-resistant foam. BC powder. Carbon dioxide.
Unsuitable extinguishing media
: No unsuitable extinguishing media known.
5.2. Special hazards arising from the substance or mixture

Fire hazard
: DIRECT FIRE HAZARD. Material presenting a fire hazard. INDIRECT FIRE HAZARD.
Temperature above flashpoint: higher fire/explosion hazard. Reactions involving a fire hazard:
see "Reactivity Hazard".

Explosion hazard
: INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".
Reactivity
: Upon combustion: CO and CO2 are formed. Reacts violently with (strong) oxidizers: (increased)
risk of fire/explosion. Reacts violently with many compounds. Reacts with (some) acids: release
of (highly) toxic compounds. Unstabilized product polymerizes. Reacts with (some) bases:
release of carbon dioxide with pressure rise and possible bursting of container.

5.3. Advice for firefighters

Firefighting instructions
: Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to
heat. Take account of toxic fire-fighting water. Use water moderately and if possible collect or
contain it.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment
: Gas-tight suit. Corrosion-proof suit.
Emergency procedures
: Keep upwind. Mark the danger area. Consider evacuation. Close doors and windows of adjacent
premises. No naked flames. Keep containers closed. Wash contaminated clothes.

6.1.2. For emergency responders

Protective equipment
: Equip cleanup crew with proper protection. Do not breathe gas, fumes, vapour or spray.
Emergency procedures
: If a major spill occurs, all personnel should be immediately evacuated and the area ventilated.
Ventilate area. Stop leak if safe to do so.

6.2. Environmental precautions

Prevent soil and water pollution. Prevent spreading in sewers.
Safety Data Sheets (SDS) Explained -_3
Formaldehyde, 37% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

03/05/2014 EN (English) 4/12

6.3. Methods and material for containment and cleaning up

For containment
: Contain released substance, pump into suitable containers. Consult "Material-handling" to select
material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to reduce
evaporation. Dilute toxic gases/vapours with water spray. Take account of toxic/corrosive
precipitation water.

Methods for cleaning up
: Take up liquid spill into absorbent material, e.g.: dry sand/earth/vermiculite. Scoop absorbed
substance into closing containers. See "Material-handling" for suitable container materials.
Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Take collected spill
to manufacturer/competent authority. Clean contaminated surfaces with an excess of water.
Wash clothing and equipment after handling.

6.4. Reference to other sections

No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling
: Comply with the legal requirements. Use only in well-ventilated areas. Remove contaminated
clothing immediately. Clean contaminated clothing. Keep the substance free from contamination.
Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Use
earthed equipment. Keep away from naked flames/heat. At temperature > flashpoint: use spark-
/explosionproof appliances. Finely divided: spark- and explosionproof appliances. Finely divided:
keep away from ignition sources/sparks. Observe very strict hygiene - avoid contact. Keep
container tightly closed. Measure the concentration in the air regularly. Exhaust gas must be
neutralised.

Hygiene measures
: Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with
mild soap and water before eating, drinking or smoking and when leaving work. Wash
contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the
workplace.

7.2. Conditions for safe storage, including any incompatibilities

Incompatible products
: Strong oxidizers. Strong bases. metals. Acid chlorides. Acid anhydrides.
Incompatible materials
: Sources of ignition.
Heat and ignition sources
: KEEP SUBSTANCE AWAY FROM: heat sources.
Prohibitions on mixed storage
: KEEP SUBSTANCE AWAY FROM: combustible materials. oxidizing agents. (strong) acids.
(strong) bases.

Storage area
: Store in a cool area. Keep container in a well-ventilated place. Keep locked up. Provide for a tub
to collect spills. Unauthorized persons are not admitted. Meet the legal requirements.

Special rules on packaging
: SPECIAL REQUIREMENTS: closing. clean. correctly labelled. meet the legal requirements.
Secure fragile packagings in solid containers.

Packaging materials
: SUITABLE MATERIAL: stainless steel. aluminium. synthetic material. glass.
stoneware/porcelain. MATERIAL TO AVOID: iron. copper. zinc. nickel.

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Formaldehyde, 37% w/w (50-00-0)

USA ACGIH
ACGIH Ceiling (mg/m³) 0.37 mg/m³
USA ACGIH
ACGIH Ceiling (ppm) 0.3 ppm
USA OSHA
OSHA PEL (TWA) (ppm) 0.75 ppm
USA OSHA
OSHA PEL (STEL) (ppm) 2 ppm
Formaldehyde (50-00-0)

USA ACGIH
ACGIH Ceiling (mg/m³) 0.37 mg/m³
USA ACGIH
ACGIH Ceiling (ppm) 0.3 ppm
USA OSHA
OSHA PEL (TWA) (ppm) 0.75 ppm
USA OSHA
OSHA PEL (STEL) (ppm) 2 ppm
Methanol (67-56-1)

USA ACGIH
ACGIH TWA (ppm) 200 ppm
Safety Data Sheets (SDS) Explained -_4

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